WEBVTT

1
00:00:00.000 --> 00:00:09.253
Here is the problem: Find the pH of a 0.02 M weak base with Kb equals 0.00056.

2
00:00:09.703 --> 00:00:18.178
Convert between hydrogen ion concentration, hydroxide concentration, pH and pOH in water at 25 °C.

3
00:00:18.978 --> 00:00:29.299
Set up the equilibrium (ICE table). x is the equilibrium concentration of OH to the power minus, which equals the amount that ionised.

4
00:00:29.749 --> 00:00:31.595
Solve the quadratic exactly.

5
00:00:32.045 --> 00:00:41.844
Percent ionisation. Above 5 percent, so the shortcut x approximately the square root of KC would be noticeably wrong; the exact quadratic is needed.

6
00:00:42.294 --> 00:00:45.150
pOH from [OH to the power minus ].

7
00:00:45.950 --> 00:00:46.844
pH.

8
00:00:47.294 --> 00:00:56.524
pOH and [OH to the power minus ] (25 °C, Kw equals 1.0 times 10 to the power minus 14).

9
00:00:57.324 --> 00:01:17.374
So the answer is pH equals 11.49, pOH equals 2.512, [H to the power plus ] equals 3.249 times 10 to the power negative 12 M, [OH to the power minus ] equals 0.00307833 M (basic).

10
00:01:17.824 --> 00:01:30.816
pH is a logarithmic scale: each unit is a tenfold change in hydrogen ion concentration. Below 7 the solution is acidic, above 7 it is basic, at 25 °C.

11
00:01:31.616 --> 00:01:42.646
[H to the power plus ][OH to the power minus ] equals 1 times 10 to the power negative 14 approximately 1.0 times 10 to the power negative 14.

12
00:01:43.095 --> 00:01:44.535
The solution is basic.
